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2 article(s) from Magri, Andrea

Phenalenyl-based mononuclear dysprosium complexes

Yanhua Lan,
Andrea Magri,
Olaf Fuhr and
Mario Ruben

Beilstein J. Nanotechnol. 2016, 7, 995–1009, doi:10.3762/bjnano.7.92

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Scheme 1: Synthesis of complexes 1–3. (a) NaH, 1/3DyCl₃·6H₂O, EtOH, reflux then stirring at RT overnight. (b)...

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Scheme 2: Synthesis of complex 4 under anhydrous conditions. The proposed structure of the complex is based o...

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Figure 1: Molecular structure of complex 1 obtained by single crystal X-ray diffraction. Hydrogen atoms are o...

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Figure 2: Molecular structure of complex 2 obtained by single crystal X-ray diffraction. Hydrogen atoms are o...

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Figure 3: Molecular structure of complex 3 obtained by single crystal X-ray diffraction. Hydrogen atoms are o...

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Figure 4: Absorption spectra of the three dysprosium complexes in diluted (2 × 10⁻⁶ M) DMSO solutions of 1–4 ...

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Figure 5: (Top) Temperature dependence of out-of-phase component of ac magnetic susceptibility under zero dc ...

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Figure 6: Orientation of the main anisotropy axis in complexes 1–3 indicated as blue arrows (a, b and c) calc...

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Figure 7: Cole–Cole plots under zero or different dc fields in the given temperature ranges. Sample codes are...

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Full Research Paper

Published 08 Jul 2016

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Charge carrier mobility and electronic properties of Al(Op)₃: impact of excimer formation

Andrea Magri,
Pascal Friederich,
Bernhard Schäfer,
Valeria Fattori,
Xiangnan Sun,
Timo Strunk,
Velimir Meded,
Luis E. Hueso,
Wolfgang Wenzel and
Mario Ruben

Beilstein J. Nanotechnol. 2015, 6, 1107–1115, doi:10.3762/bjnano.6.112

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Figure 1: Tris(1-oxo-1H-phenalen-9-olate)aluminum(III) (Al(Op)₃) structure. H atoms are omitted for clarity.

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Figure 2: Cyclic voltammogram for Al(Op)₃ recorded at room temperature in CH₂Cl₂ solution using TBAPF₆ as the...

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Figure 3: Absorption (dotted line) and emission spectra (solid line) of Al(Op)₃ in CH₂Cl₂ solution (black) an...

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Figure 4: Luminescence decay in CH₂Cl₂ solution (black) and as a thin film on quartz (red). In solution, a mo...

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Figure 5: Transfer curve of the Al(Op)₃-based TFT with a channel length of 100 μm. In this figure, I_DS and V_DS...

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Figure 6: Comparison of the source–drain current (I_DS) and the leakage gate current (I_G) from the transfer ch...

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Figure 7: a) HOMO (left) and LUMO (right) orbitals of Al(Op)₃ calculated with TURBOMOLE [36] on a B3-LYP [37]/SV(P) [38] ...

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Figure 8: Energy levels of Al(Op)₃ calculated with different conditions, namely, HOMO and LUMO in vacuum (vac...

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Full Research Paper

Published 05 May 2015

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Phenalenyl-based mononuclear dysprosium complexes

Charge carrier mobility and electronic properties of Al(Op)3: impact of excimer formation

Charge carrier mobility and electronic properties of Al(Op)₃: impact of excimer formation